FURTHER STRUCTURAL STUDIES ON THE PETROFORMYNES

被引：25

作者：

GUO, YW ^{[1
]}

GAVAGNIN, M ^{[1
]}

TRIVELLONE, E ^{[1
]}

CIMINO, G ^{[1
]}

机构：

[1] CNR,IST CHIM MOLEC INTERESSE BIOL,I-80072 ARCO,ITALY

来源：

JOURNAL OF NATURAL PRODUCTS-LLOYDIA | 1995年 / 58卷 / 05期

关键词：

D O I：

10.1021/np50119a009

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Petroformynes are unusual metabolites contained in the Mediterranean sponge Petrosia ficiformis. The structure and absolute stereochemistry of the most abundant of these compounds, which display long unbranched alkyl chains, have only recently been rigorously proven. The structures of twelve minor compounds are now reported, providing a better understanding of the chemistry of P. ficiformis. In addition, complete spectroscopic characterization of eleven partial structures (a-k) frequently contained in P. ficiformis metabolites is provided as an aid to future structure elucidation among compounds of this type.

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页码：712 / 722

页数：11

相关论文

共 15 条

[1] FURTHER BIOACTIVE ACETYLENIC-COMPOUNDS FROM THE CARIBBEAN SPONGE CRIBROCHALINA-VASCULUM [J].

AIELLO, A ;

FATTORUSSO, E ;

MENNA, M .

JOURNAL OF NATURAL PRODUCTS, 1992, 55 (09) :1275-1280

[2]

[Anonymous], 1971, PROBIT ANAL

[3] HIGH MOLECULAR-WEIGHT POLYACETYLENES FROM THE NUDIBRANCH PELTODORIS-ATROMACULATA AND THE SPONGE PETROSIA-FICIFORMIS [J].

CASTIELLO, D ;

CIMINO, G ;

DEROSA, S ;

DESTEFANO, S ;

SODANO, G .

TETRAHEDRON LETTERS, 1980, 21 (52) :5047-5050

[4] POLYACETYLENES FROM THE SPONGE PETROSIA-FICIFORMIS FOUND IN DARK CAVES [J].

CIMINO, G ;

CRISPINO, A ;

DEROSA, S ;

DESTEFANO, S ;

SODANO, G .

EXPERIENTIA, 1981, 37 (09) :924-926

[5] MINOR BIOACTIVE POLYACETYLENES FROM PETROSIA-FICIFORMIS [J].

CIMINO, G ;

DEGIULIO, A ;

DEROSA, S ;

DIMARZO, V .

JOURNAL OF NATURAL PRODUCTS, 1990, 53 (02) :345-353

[6] HIGH MOLECULAR-WEIGHT POLYACETYLENES FROM PETROSIA-FICIFORMIS - FURTHER STRUCTURAL-ANALYSIS AND BIOLOGICAL-ACTIVITY [J].

CIMINO, G ;

DEGIULIO, A ;

DEROSA, S ;

DIMARZO, V .

TETRAHEDRON LETTERS, 1989, 30 (27) :3563-3566

[7] FURTHER HIGH MOLECULAR-WEIGHT POLYACETYLENES FROM THE SPONGE PETROSIA-FICIFORMIS [J].

CIMINO, G ;

DEGIULIO, A ;

DEROSA, S ;

DESTEFANO, S ;

SODANO, G .

JOURNAL OF NATURAL PRODUCTS, 1985, 48 (01) :22-27

[8] ANTIFUNGAL BROMINATED C-18 ACETYLENIC ACIDS FROM THE MARINE SPONGE, PETROSIA-VOLCANO HOSHINO [J].

FUSETANI, N ;

LI, HY ;

TAMURA, K ;

MATSUNAGA, S .

TETRAHEDRON, 1993, 49 (06) :1203-1210

[9] ABSOLUTE STEREOCHEMISTRY OF PETROFORMYNES, HIGH-MOLECULAR POLYACETYLENES FROM THE MARINE SPONGE PETROSIA-FICIFORMIS [J].

GUO, YW ;

GAVAGNIN, M ;

TRIVELLONE, E ;

CIMINO, G .

TETRAHEDRON, 1994, 50 (46) :13261-13268

[10] SYNTHESIS OF SOME BIOACTIVE ACETYLENIC ALCOHOLS, COMPONENTS OF THE MARINE SPONGE CRIBROCHALINA-VASCULUM [J].

KULKARNI, BA ;

CHATTOPADHYAY, S ;

CHATTOPADHYAY, A ;

MAMDAPUR, VR .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (22) :5964-5966