THE FORMATION OF MONOMERIC AND DIMERIC NITRO NITRATES IN THE REACTION OF PHENANTHRENE WITH NITROGEN-DIOXIDE - X-RAY CRYSTAL-STRUCTURE OF TRANS-10-NITRO-9,10-DIHYDROPHENANTHREN-9-YL NITRATE

被引：11

作者：

JUDD, MC

HARTSHORN, MP

MARTYN, RJ

ROBINSON, WT

WRIGHT, GJ

VANNOORT, RW

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

[2] DSIR,ILAM RES CTR,DIV CHEM,CHRISTCHURCH,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 01期

关键词：

D O I：

10.1071/CH9900125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of phenanthrene (1) with nitrogen dioxide in benzene solution gives the dimeric nitro nitrate (3), trans and cis nitro nitrates (7) and (8), and 9-nitro- (4), 3-nitro- (5) and 1-nitro-phenanthrene (6). The X-ray crystal structure of the trans nitro nitrate (7) is reported. The effect of the phenanthrene (1) concentration on product yields is reported. Gas-liquid chromatography results for the nitro nitrates (3) and (7) point to difficulties in using this technique for product analyses in reactions of phenanthrene (1) with nitrogen dioxide. © 1990 ASEG.

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页码：125 / 132

页数：8

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