PREPARATION AND PROPERTIES OF POLY(ENARYLOXY NITRILES) CONTAINING SCHIFF-BASES

被引：11

作者：

KIM, SG ^{[1
]}

LEE, SJ ^{[1
]}

GONG, MS ^{[1
]}

机构：

[1] DANKOOK UNIV,DEPT CHEM,CHUNGNAM 330714,SOUTH KOREA

来源：

MACROMOLECULES | 1995年 / 28卷 / 16期

关键词：

D O I：

10.1021/ma00120a032

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(enaryloxy nitriles) containing Schiff bases were prepared by reacting p-bis(1-chloro-2,2-dicyanovinyl)benzene (2) with p-hydroxybenzaldehyde, which were then polymerized with various aromatic diamines. The chemical structure of the polymers was confirmed through syntheses of their corresponding Schiff base-containing model compounds. All the polymers were soluble in polar aprotic solvents such as DMF, DMSO, DMAc, and NMP. Moderate molecular weight polymers possessing M(w) in the range 11000-21000 were obtained, and brittle films were cast from DMF solution. They showed a large exotherm around 340 degrees C attributable to the chemical changes of the dicyanovinyl group. Especially, curing of the azomethine group was observed to occur at 390 degrees C by differential scanning calorimetry. According to the thermogravimetric analyses, the polymers exhibited excellent thermal stability with 80-95% residual weight at 500 degrees C under nitrogen.

引用

页码：5638 / 5642

页数：5