EXCHANGE INTERACTION IN HYBRID SPIN SYSTEMS - CHLOR-MESO-TETRAPHENYLPORPHYRINATOCHROMIUM(III) DERIVATIVES LIGATED WITH 3-(N-OXY-N-TERT-BUTYLAMINO)PYRIDINES AND 4-(N-OXY-N-TERT-BUTYLAMINO)PYRIDINES

被引：31

作者：

KITANO, M ^{[1
]}

KOGA, N ^{[1
]}

IWAMURA, H ^{[1
]}

机构：

[1] UNIV TOKYO,GRAD SCH SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 04期

关键词：

D O I：

10.1039/c39940000447

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 3d electrons of chromium(lll) and the unpaired electron of the nitroxide radical interact ferro- and antiferro-magnetically in chloro-meso-tetraphenylporphyrinatochrom ligated with 3- and 4-(N-oxy-N-tert-butylamino)pyridines to produce quintet and triplet ground states, respectively.

引用

页码：447 / 448

页数：2

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