COORDINATION-COMPLEXES OF BIS(TRIPHENYLPHOSPHINE) COPPER(I) CARBONATE AND BICARBONATE

被引：22

作者：

DARENSBOURG, DJ

HOLTCAMP, MW

KHANDELWAL, B

REIBENSPIES, JH

机构：

[1] Department of Chemistry, Texas A&M University, Texas 77843, College Station

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 21期

关键词：

D O I：

10.1021/ic00125a047

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solid-state structures of dimeric bis(triphenylphosphine)copper(I) carbonate and bicarbonate have been determined by X-ray crystallography. The bicarbonate complex possesses an uncommon mode of carbonate or carboxylate binding. That is, the two Cu(I) ions are bridged by two oxygen atoms, one from each of two bicarbonate ligands. This bonding interaction is complemented by strong intermolecular hydrogen-bonding.

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页码：5390 / &

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