NEW CHIRAL 1,1'-BIS(PHOSPHOLANO)FERROCENE LIGANDS FOR ASYMMETRIC CATALYSIS

被引：91

作者：

BURK, MJ

GROSS, MF

机构：

[1] Department of Chemistry, Duke University, P.M. Gross Chemical Laboratory, Durham

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)78543-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of two new 1,1'-bis(phospholano)ferrocene ligands are described. Preliminary catalytic studies showed that enantioselectivities as high as 83% ee could be achieved in the hydrogenation of several model olefin, ketone, and hydrazone substrates.

引用

页码：9363 / 9366

页数：4

共 15 条

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[6] EFFICIENT RHODIUM-CATALYZED HYDROGENATION OF ALDEHYDES AND KETONES
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[9] CATALYTIC ASYMMETRIC REDUCTIVE AMINATION OF KETONES VIA HIGHLY ENANTIOSELECTIVE HYDROGENATION OF THE C=N DOUBLE-BOND
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