ELECTRICAL CONDUCTANCE OF LIQUID AND SUPERCRITICAL WATER EVALUATED FROM 0-DEGREES-C AND 0.1 MPA TO HIGH-TEMPERATURES AND PRESSURES - REDUCED-STATE RELATIONSHIPS

被引:40
作者
MARSHALL, WL
机构
[1] Oak Ridge Natl Lab, Oak Ridge, TN,, USA, Oak Ridge Natl Lab, Oak Ridge, TN, USA
关键词
HIGH PRESSURE ENGINEERING - HIGH TEMPERATURE ENGINEERING - WATER - Electric Conductivity;
D O I
10.1021/je00048a027
中图分类号
O414.1 [热力学];
学科分类号
摘要
The electrical conductance of liquid and supercritical water to high temperatures and pressures is represented by an equation that incorporates some earlier observed trends and a newly discovered reduced-state relationship presented here. Calculations with the equation are believed to describe within plus or minus 1 to plus or minus 5% the specific conductance of liquid water at temperatures from 0 to 374 degree C and at pressures from saturated vapor pressure to 1000 MPa (10 kbar). For supercritical water at fluid densities from about 0. 3 to 1 g cm** minus **3 and at temperatures from 374 to 1000 degree C, the uncertainties probably will increase from 5% to perhaps 15% at the highest temperatures and pressures.
引用
收藏
页码:221 / 226
页数:6
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