POLYMERIC PHOTOINITIATORS BEARING SIDE-CHAIN ACYLDIPHENYLPHOSPHINOXIDE MOIETIES FOR UV SURFACE-COATINGS

被引：9

作者：

ANGIOLINI, L

CARETTI, D

CARLINI, C

LELLI, N

ROLLA, PA

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM IND & MAT,VIALE RISORGIMENTO 4,I-40136 BOLOGNA,ITALY

[2] UNIV PISA,DIPARTIMENTO FIS,CONSORZIO INFM,I-56100 PISA,ITALY

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1993年 / 48卷 / 07期

关键词：

D O I：

10.1002/app.1993.070480704

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymeric photoinitiators bearing side-chain acyldiphenylphosphinoxide moieties have been prepared by reacting poly(methacryloyl chloride) and methacryloyl chloride/methyl methacrylate copolymers with methoxydiphenylphosphine. The activity of the above polymeric systems has been checked in the UV curing of both clear and pigmented coating formulations and compared with that of the low molecular weight analog pivaloyldiphenylphosphinoxide. The stability to light and to different hydrolitic conditions of the polymeric photoinitiators with respect to pivaloyldiphenylphosphinoxide has also been tested. The data concerning activity and stability are discussed in terms of structural features of the above systems.

引用

页码：1163 / 1175

页数：13

共 35 条

[1] OPTICALLY-ACTIVE POLYMERS CONTAINING SIDE-CHAIN AZOBENZENE CHROMOPHORES - CHIROPTICAL PROPERTIES AND PHOTOCHROMIC BEHAVIOR OF 4-METHACRYLOXYAZOBENZENE (-)-MENTHYL METHACRYLATE COPOLYMERS [J].