MONONUCLEAR RUTHENIUM(III) COMPLEXES OF THE TYPE LRUX(3) (X=CL-, NCO-, NCS-, N-3(-) L=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)

被引：14

作者：

SCHNEIDER, R

JUSTEL, T

WIEGHARDT, K

NUBER, B

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,D-44780 BOCHUM,GERMANY

[2] UNIV HEIDELBERG,INST ANORGAN CHEM,D-69120 HEIDELBERG,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 03期

关键词：

MONONUCLEAR RU(III) COMPLEXES; SYNTHESIS; CRYSTAL STRUCTURE; ELECTROCHEMISTRY;

D O I：

10.1515/znb-1994-0307

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chloro ligands in [LRuCl(3)] (1), the crystal structure of which has been determined, are readily substituted in aqueous solution by NCO-, NCS-, and N-3(-) with formation of LRu(III)X(3) complexes. [LRu(II)(N-3)(3)] is very thermolabile and light sensitive and forms diamagnetic [LRu(II)(N-3)(2)(N-2)]. The thiocyanate species probably contains N- and S-coordinated NCS-ligands: [LRu(NCS)(2)(SCN)]. The electrochemistry of the new complexes is reported.

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页码：330 / 336

页数：7

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