CLAISEN REARRANGEMENT OF ALPHA-(F-ALKYL)ENOL ETHERS PREPARED VIA WITTIG OLEFINATION OF ALLYL PERFLUOROALKANOATES

被引：12

作者：

BEGUE, JP ^{[1
]}

BONNETDELPON, D ^{[1
]}

WU, SW ^{[1
]}

MBIDA, A ^{[1
]}

SHINTANI, T ^{[1
]}

NAKAI, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM TECHNOL,MEGURO KU,TOKYO 152,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(00)76656-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title rearrangement is shown to proceed at ca. 100 degrees C to afford the gamma,delta-unsaturated perfluoroalkyl ketones. The stereochemistry of the Wittig and claisen processes and the effect of the Rf-group in the Claisen process are discussed.

引用

页码：2907 / 2910

页数：4

共 14 条

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