A SIMPLE, EFFECTIVE, NEW, PALLADIUM-CATALYZED CONVERSION OF ENOL SILANES TO ENONES AND ENALS

被引：188

作者：

LAROCK, RC ^{[1
]}

HIGHTOWER, TR ^{[1
]}

KRAUS, GA ^{[1
]}

HAHN, P ^{[1
]}

ZHENG, D ^{[1
]}

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,TOXICOL PROGRAM,AMES,IA 50011

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 14期

关键词：

D O I：

10.1016/0040-4039(95)00306-W

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enol silanes derived from aldehydes and ketones are readily converted to the corresponding alpha,beta-unsaturated carbonyl compounds by 10% Pd(OAc)(2) in the presence of one atmosphere of oxygen in DMSO as the solvent.

引用

页码：2423 / 2426

页数：4

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