BEHAVIOR OF LITHIUM-ELECTROLYTE INTERFACE DURING CYCLING IN SOME ETHER-CARBONATE AND CARBONATE MIXTURES

被引：42

作者：

FRINGANT, C

TRANCHANT, A

MESSINA, R

机构：

[1] Laboratoire d'Electrochimie Catalyse et Synthe`se Organique, UMR 28, CNRS, 94320 Thiais

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 04期

关键词：

LITHIUM-ELECTROLYTE INTERFACE; LIPF6; ETHER-CARBONATE MIXTURES; CYCLING EFFICIENCY; MORPHOLOGY;

D O I：

10.1016/0013-4686(94)00199-B

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Cycling behavior of lithium in PC(propylene carbonate)-EC(ethylene carbonate)DME(dimethoxyethane) and PC-EC-DMC(dimethylcarbonate)-based electrolytes has been investigated and correlated with electrode morphology and impedance parameters. Better cycling efficiencies have been obtained in PC-EC-DMC mixtures. A higher stability of the lithium-electrolyte interface in these mixtures has been produced through the evolution of film resistances and through the structure of electroplated lithium. Impedance spectroscopy allowed us to study the modification of the lithium-electrolyte interface during cycling. We observed unusual behavior of the interface in LiPF6-based electrolytes involving the formation of an electroactive passivating layer.

引用

页码：513 / 523

页数：11

共 29 条

[1] Abraham K. M., 1983, LITHIUM BATTERIES
[2] IMPEDANCE SPECTROSCOPY OF LITHIUM ELECTRODES .1. GENERAL BEHAVIOR IN PROPYLENE CARBONATE SOLUTIONS AND THE CORRELATION TO SURFACE-CHEMISTRY AND CYCLING EFFICIENCY
AURBACH, D
ZABAN, A
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 348 (1-2): : 155 - 179
[3] IDENTIFICATION OF SURFACE-FILMS FORMED ON LITHIUM IN DIMETHOXYETHANE AND TETRAHYDROFURAN SOLUTIONS
AURBACH, D
DAROUX, ML
FAGUY, PW
YEAGER, E
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (08) : 1863 - 1871
[4] THE CORRELATION BETWEEN SURFACE-CHEMISTRY, SURFACE-MORPHOLOGY, AND CYCLING EFFICIENCY OF LITHIUM ELECTRODES IN A FEW POLAR APROTIC SYSTEMS
AURBACH, D
GOFER, Y
LANGZAM, J
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (11) : 3198 - 3205
[5] THE BEHAVIOR OF LITHIUM ELECTRODES IN MIXTURES OF ALKYL CARBONATES AND ETHERS
AURBACH, D
GOFER, Y
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (12) : 3529 - 3536
[6] THE BEHAVIOR OF LITHIUM ELECTRODES IN PROPYLENE AND ETHYLENE CARBONATE - THE MAJOR FACTORS THAT INFLUENCE LI CYCLING EFFICIENCY
AURBACH, D
GOFER, Y
BENZION, M
APED, P
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 339 (1-2): : 451 - 471
[7] AURBACH D, 1987, J ELECTROCHEM SOC, V134, P1613
[8] de Levie R., 1967, ADV ELECTROCH EL ENG
[9] FROMENT M, 1979, J MICROSC SPECT ELEC, V4, P111
[10] GARREAU M, 1978, J MICROSC SPECT ELEC, V3, P27

← 1 2 3 →