SYNTHESES AND STRUCTURES OF DICYANOBIS (OXAZOLIDIN-2-YLIDENE)PALLADIUM(II) AND PLATINUM(II) COMPLEXES

被引：30

作者：

KERNBACH, U ^{[1
]}

FEHLHAMMER, WP ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST ANORGAN & ANALYT CHEM,D-14195 BERLIN,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1995年 / 235卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; PALLADIUM COMPLEXES; PLATINUM COMPLEXES; CARBENE COMPLEXES;

D O I：

10.1016/0020-1693(95)90071-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(2-Trimethylsiloxy)ethyl isocyanide reacts with Pd(CN)(2) and Pt(CN)(2) to give trans-[Pd(CN)(2)(CN(H)CH2CH2O)(2)] (1), trans-[Pt(CN)(2)(CN(H)CH2CH2O)(2)] (2) and cis-[Pt(CN)(2)(CN(H)CH2CH2O)(2)] (3), respectively. Complexes 1-3 have been characterized by crystal structure determinations. In the cis compound 3, the carbene ligands are linked by NH ... O hydrogen bonds. A measured Pt ... Pt distance of 3.2828(6) Angstrom in this crystal structure indicates a weak Pt ... Pt interaction.

引用

页码：299 / 305

页数：7

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