ELECTROOPTIC PROPERTIES OF SIDE-CHAIN POLYIMIDES WITH EXCEPTIONAL THERMAL STABILITIES

被引:69
作者
VERBIEST, T [1 ]
BURLAND, DM [1 ]
JURICH, MC [1 ]
LEE, VY [1 ]
MILLER, RD [1 ]
VOLKSEN, W [1 ]
机构
[1] IBM CORP, ALMADEN RES CTR, DIV RES, SAN JOSE, CA 95120 USA
关键词
D O I
10.1021/ma00112a060
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A class of thermoplastic side-chain polyimides was described which have exceptional thermal stabilities without significant sacrifice of optical nonlinearity. Also, a quite general approach to the synthesis of thermally stable electrooptic polymers with high optical nonlinearities was demonstrated. The nonlinearity is optimized by choice of the chromophore from which the diamine monomer is synthesized, while physical properties such as the glass transition temperature and processability can be optimized by careful choice of the dianhydride portion of the polyimide.
引用
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页码:3005 / 3007
页数:3
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