CONCAVE REAGENTS .5. BIMACROCYCLIC 1,10-PHENANTHROLINE CYCLOPHANES

被引：43

作者：

LUNING, U

MULLER, M

机构：

[1] Chemisches Laboratorium, Universität Freiburg, D-7800

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 03期

关键词：

Concave base / Macrocycle / 1,10‐Phenanthroline / Cyclophane / Aryl lithium compounds;

D O I：

10.1002/cber.19901230335

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of lithium aryls 3 to 1,10‐phenanthroline (2), functionalization of the rearomatized bisadduct 8b to the tetraphenol 8d, and cyclization of 8d with two equivalents of an α,ω‐ditosylate 9 led to a highly symmetrical, conformer‐free bimacrocyclic 1,10‐phenanthroline 10a in which the basic and coordinating region possesses a concave shielding. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

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页码：643 / 645

页数：3

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