SYNTHESIS AND STRUCTURE OF THE 1ST PHOSPHINE OXIDE COMPLEX OF COPPER(I) - EVIDENCE FOR A MARKED BORDERLINE CHARACTER OF THE METAL CENTER

被引:59
作者
PILLONI, G
CORAIN, B
DEGANO, M
LONGATO, B
ZANOTTI, G
机构
[1] CNR,CTR STUDIO STABIL & REATTIV COMPOSTI COORDINAZ,I-35131 PADUA,ITALY
[2] CNR,CTR STUDIO BIOPOLIMERI,I-35131 PADUA,ITALY
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 11期
关键词
D O I
10.1039/dt9930001777
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The remarkable stability of [Cu(dppf)(odppf)]BF4 [dppf = 1,1'-bis(diphenylphosphino)ferrocene, odppf = 1,1'-bis(oxodiphenylphosphoranyl)ferrocene], characterized in the solid state by X-ray analysis and in solution by P-31 NMR spectroscopy, reveals a marked borderline character of copper(I).
引用
收藏
页码:1777 / 1778
页数:2
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