FREE-ENERGY OF NONEQUILIBRIUM POLARIZATION SYSTEMS .4. A FORMALISM BASED ON THE NONEQUILIBRIUM DIELECTRIC DISPLACEMENT

被引：85

作者：

MARCUS, RA

机构：

[1] Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 29期

关键词：

D O I：

10.1021/j100080a012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An expression for the free energy of nonequilibrium polarization systems, valid in the presence or absence of dielectric images, is derived using the nonequilibrium dielectric displacement and electric field vectors. The results are compared with those based on the nonequilibrium polarization vector (Part I). For the case of longitudinal polarization they are equivalent. However, the present expression is simpler and more compact. The results are compared with others in the literature.

引用

页码：7170 / 7174

页数：5

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