INTRAMOLECULAR SWITCHING BETWEEN DIPOLAR RESONANCE STRUCTURES IN SINGLET AND TRIPLET EXCITED-STATES DETECTED BY TRMC

被引：25

作者：

WARMAN, JM

SCHUDDEBOOM, W

JONKER, SA

DEHAAS, MP

PADDONROW, MN

ZACHARIASSE, KA

LAUNAY, JP

机构：

[1] MAX PLANCK INST BIOPHYS CHEM SPEKTROSKOPIE & PHOTOCHEM KINET,W-3400 GOTTINGEN,GERMANY

[2] CNRS,CTR ELABORAT MAT & ETUD STRUCT,F-31055 TOULOUSE,FRANCE

[3] UNIV NEW S WALES,SCH CHEM,KENSINGTON,NSW 2033,AUSTRALIA

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 210卷 / 4-6期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0009-2614(93)87044-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transient changes in the real and imaginary component of the complex permittivity of a flash-photolyzed solution can be monitored with nanosecond time resolution using the time-resolved microwave conductivity (TRMC) technique. Effects caused by rapid (picosecond), flip-flop switching between dipolar resonance structures in the S1 and T1 states of molecules with mirror symmetry have been observed.

引用

收藏

页码：397 / 404

页数：8

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