INSITU X-RAY-DIFFRACTION AND X-RAY ABSORPTION INVESTIGATIONS OF METHANOL SYNTHESIS CATALYSTS DERIVED FROM CECU2

被引:18
作者
SHAW, EA
RAYMENT, T
WALKER, AP
LAMBERT, RM
GAUNTLETT, T
OLDMAN, RJ
DENT, A
机构
[1] ICI CHEM & POLYMERS LTD,RUNCORN WA7 4QE,CHESHIRE,ENGLAND
[2] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND
[3] SERC,DARESBURY LAB,WARRINGTON WA4 4AD,CHESHIRE,ENGLAND
关键词
D O I
10.1016/0920-5861(91)85024-3
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
New information about the structure of methanol synthesis catalysts derived from CeCu2 has been obtained from in situ XRD measurements and XA spectra recorded at the Cu K and Ce L(III) edges. The active site involves metallic copper and highly defective trivalent cerium oxide.
引用
收藏
页码:197 / 202
页数:6
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