STRUCTURE OF AQUABIS(2,2'-BIPYRIDYL)ZINC(II) DIPERCHLORATE

被引：15

作者：

LIU, M

ARORA, SK

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192009478

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Zn atom is pentacoordinated involving four N atoms of the bipyridyl ligands and an O atom in nearly trigonal bipyrimidal arrangement. The 2,2'-bipyridyl groups are planar and make an angle of 115.2-degrees with each other. Hydrogen bonding exists involving O(9) of the cation and O(5) of a perchlorate anion.

引用

收藏

页码：372 / 374

页数：3

相关论文

共 7 条

[1] APPLICATION OF PHASE RELATIONSHIPS TO COMPLEX STRUCTURES .3. OPTIMUM USE OF PHASE RELATIONSHIPS [J].

GERMAIN, G ;

MAIN, P ;

WOOLFSON, MM .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1971, A 27 (JUL1) :368-&

[2]

JOHNSON CK, 1976, ORNL5138 REP

[3]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[4] STRUCTURES OF DIETHYLENETRIAMINECOPPER(2) CATIONS .I. CRYSTAL STRUCTURE OF BIS(DIETHYLENETRIAMINE)COPPER(2) NITRATE [J].

STEPHENS, FS .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (06) :883-&

[5] CRYSTAL AND MOLECULAR STRUCTURE OF BISNITRITO-2,2'-BIPYRIDYLCOPPER(2) [J].

STEPHENS, FS .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (14) :2081-&

[6]

STEPHENS FS, 1969, J CHEM SOC DA, P1248

[7] THE STRUCTURES OF BIS(2,2'-BIPYRIDYL)MONONITRITOCOPPER(II) TETRAFLUOROBORATE BIS(2,2'-BIPYRIDYL)MONONITRITOZINC(II) NITRATE [J].

WALSH, A ;

WALSH, B ;

MURPHY, B ;

HATHAWAY, BJ .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (AUG) :1512-1520