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SURFACE MODIFICATION OF POLYMERS .1. GRAFTING INITIATED BY PHOTO-GENERATED HYDROPEROXIDES
被引：23
作者：
GEUSKENS, G
KANDA, MN
机构：
[1] Université Libre de Bruxelles, 1050 Brussels, Campus Plaine CP 206-1, Boulevard Triomphe
关键词：
D O I：
10.1016/0014-3057(91)90026-K
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ;
080501 ;
081704 ;
摘要：
Grafting of methacrylic acid (and other water-soluble monomers such as acrylic acid and acrylamide) onto the surface of styrene-butadiene-styrene block copolymer films has been performed using polymeric hydroperoxides as initiator. These peroxides are obtained by reaction with the polymer of singlet oxygen, the production of which is photo-sensitized by anthracene. The rate of grafting is first order with respect to the monomer concentration in solution but increase of rate is observed for methacrylic acid concentrations higher than 1 mol l-1. The rate of grafting is also proportional to the initial concentration of anthracene in the film.
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页码：877 / 879
页数：3
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