SOME ASPECTS OF DIFFUSION - FLUCTUATIONS IN REACTION DIFFUSION, AND GEOMETRIC INFLUENCES IN NONUNIFORM MEDIA

被引:3
作者
FRISCH, HL [1 ]
KIMBALL, JC [1 ]
机构
[1] SUNY ALBANY,DEPT PHYS,ALBANY,NY 12222
来源
THEORETICA CHIMICA ACTA | 1992年 / 82卷 / 05期
关键词
DIFFUSION-REACTION; TRANSPORT; TIME LAG; FRACTAL FOAMS; LOW DENSITY MICROCELLULAR MATERIALS;
D O I
10.1007/BF01113937
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We deal with two diffusion problems: Space-integrated conserved entities characterizing very fast - diffusion - controlled reactions, such as time lags, etc. are universal. They are given by relationships which do not reflect the failure of the mean field hydrodynamic equations. We present another application which does not reflect this failure, for determining the surface flux via a diffusion controlled reaction producing a colored product. Another anomalous diffusion process we considered is transport through cellular materials whose cell sizes are highly nonuniform. We have analyzed the effects of extreme nonuniformity by considering fractal-like models of cellular solids. The diffusion current through these models can exhibit anomalous time-dependencies which are not predicted by the diffusion equation. In particular, it is shown that the initial diffusion current can be characterized by a power-law dependence on the time. Furthermore, the exponent of the power law is given in terms of the distribution of cell sizes in the fractal-like cellular solid.
引用
收藏
页码:351 / 356
页数:6
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