PBCL2/GA BIMETAL REDOX SYSTEM-MEDIATED CARBON-CARBON BOND FORMATION REACTIONS BETWEEN CARBONYL-COMPOUNDS AND ETHYL TRICHLOROACETATE AND IODOACETONITRILE

被引：32

作者：

ZHANG, XL

HAN, Y

TAO, WT

HUANG, YZ

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,ORGANOMET CHEM LAB,SHANGHAI 200032,PEOPLES R CHINA

[2] WUHAN UNIV,DEPT CHEM,WUHAN 430072,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 03期

关键词：

D O I：

10.1039/p19950000189

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of lead dichloride and a metallic gallium bimetal redox system, carbonyl compounds reacted with ethyl trichloroacetate and iodoacetonitrile to afford ethyl beta-substituted alpha,alpha-dichloro-propionates and beta-hydroxy nitriles, respectively, in moderate to excellent yields.

引用

页码：189 / 191

页数：3

共 22 条

[1]

ARENIYADIS S, 1984, ORG REACTIONS, V31, P1

[2]

CANCEILL J, 1970, B SOC CHIM FR, P2180

[3]

GAUDEMAR M, 1972, ORGANOMET CHEM REV A, V8, P183

[4] ZINC COMPOUNDS FROM ALPHA BROMONITRILES .1. PREPARATION, STRUCTURE AND REACTIVITY WITH ALDEHYDES, KETONES AND ETHYL MANOLATE ALKYLIDENES [J].