ANODIC-OXIDATION OF THE N-CYANOMETHYL-OXAZOLIDINE SYSTEM - REGIOSELECTIVE CHLORINATION-ALPHA TO THE N,O-ACETAL FUNCTION

被引：5

作者：

MARTENS, T

SOUQUET, F

ROYER, J

机构：

[1] UNIV PARIS 05,FAC PHARM,CNRS,CHIM ANALYT & ELECTROCHIM LAB,F-75782 PARIS 06,FRANCE

[2] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 37期

关键词：

D O I：

10.1016/0040-4039(94)85030-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The anodic oxidation of the N-cyanomethyl-oxazolidine system in acetonitrile at a platinum electrode, in the presence of a mixture of chloride and bromide ions, regioselectively affords the corresponding monochloro- or dichloro- products alpha to the N,O-acetal function in goods yields.

引用

页码：6879 / 6882

页数：4

共 11 条

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