NOVEL SPIRO SUBSTITUTED CYCLOTRIPHOSPHAZENES INCORPORATING ETHYLENEDINITRAMINE UNITS

被引：10

作者：

DAVE, PR

FOROHAR, F

AXENROD, T

BEDFORD, CD

CHAYKOVSKY, M

RHO, MK

GILARDI, R

GEORGE, C

机构：

[1] CUNY CITY COLL,NEW YORK,NY 10031

[2] USN,CTR AIR WARFARE,DIV WEAP,CHINA LAKE,CA 93555

[3] USN,CTR SURFACE WARFARE,SILVER SPRING,MD 20903

[4] USN,RES LAB,STRUCT MATTER LAB,WASHINGTON,DC 20375

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 90卷 / 1-4期

关键词：

CYCLOTRIPHOSPHAZENES; NITRAMINES; NITRATION; ENERGETIC COMPOUNDS;

D O I：

10.1080/10426509408016400

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new initiative directed toward understanding the chemistry, synthesis, and properties of non or low carbon-based energetic compositions was undertaken. Initial synthesis work focused on reactions of hexachlorocyclotriphosphazene 1, with ethylenediamino and azido functional groups. The reaction of 1 with ethylenediamine, N,N'-dinitroethylenediamine, and N,N '-bis(trimethylsilyl)ethylenediamine yielded novel bis- and tris-spiro(ethylenediamino)cyclotriphosphazenes. Subsequent nitration with either nitronium tetrafluoroborate or nitric acid (100%) acetic anhydride gave various mono-, bis- and tris-spiro(N,N'-dinitroethylenediamino)cyclotriphosphazenes.

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页码：175 / 184

页数：10

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