X-RAY RESONANT RAMAN-SPECTRA OF SEVERAL COPPER-COMPOUNDS

被引：15

作者：

UDAGAWA, Y

HAYASHI, H

TOHJI, K

MIZUSHIMA, T

机构：

[1] TOHOKU UNIV, DEPT RESOURCE ENGN, SENDAI, MIYAGI 980, JAPAN

[2] TOYOHASHI UNIV TECHNOL, DEPT MAT SCI, TOYOHASHI, AICHI 440, JAPAN

来源：

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN | 1994年 / 63卷 / 05期

关键词：

X-RAY RAMAN SCATTERING; X-RAY INELASTIC SCATTERING; RESONANT SCATTERING;

D O I：

10.1143/JPSJ.63.1713

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Resonant effect in X-ray Raman spectra of various copper(I) and copper(II) compounds was studied by using tunable X-rays from synchrotron radiation. Prominent excitation energy dependence in spectral shape as well as in intensity was observed and analyzed in terms of simple equations derived from Kramers-Heisenberg equation. Anomaly in spectral shape was observed for Cu(II) compounds and it is ascribed to existence/nonexistence of a vacant 3d orbital in Cu(II)/Cu(I) compounds.

引用

页码：1713 / 1720

页数：8

共 24 条

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