1ST USE OF METHYL FORMATE WITH NO EXTRA CARBON-MONOXIDE IN THE HYDROESTERIFICATION OF ETHENE CATALYZED BY PALLADIUM COMPLEXES

被引：33

作者：

GREVIN, J ^{[1
]}

KALCK, P ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM TOULOUSE,CHIM PROCEDES,118 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 476卷 / 02期

关键词：

PALLADIUM; HYDROESTERIFICATION; ETHENE; CATALYSIS;

D O I：

10.1016/0022-328X(94)87088-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [PdH(Cl)(PBu3)2], generated in situ by addition of one equivalent of NaBH4 to [PdCl2(PBu3)2], is a good catalyst precursor for the addition of methyl formate to ethene. Extra carbon monoxide is not required, and methyl propanoate is produced with high selectivity.

引用

页码：C23 / C24

页数：2

共 16 条

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