A PC COMPATIBLE COMPUTER-PROGRAM FOR THE CALCULATION OF EQUILIBRIUM-CONSTANTS BY THE SIMULTANEOUS PROCESSING OF DIFFERENT SETS OF EXPERIMENTAL RESULTS

被引：84

作者：

VETROGON, VI ^{[1
]}

LUKYANENKO, NG ^{[1
]}

SCHWINGWEILL, MJ ^{[1
]}

ARNAUDNEU, F ^{[1
]}

机构：

[1] EHICS,CHIM PHYS LAB,CNRS,URA 405,F-67000 STRASBOURG,FRANCE

来源：

TALANTA | 1994年 / 41卷 / 12期

关键词：

D O I：

10.1016/0039-9140(94)00187-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new PC compatible computer program SIRKO for the calculation of the equilibrium constants by means of the simultaneous processing of different experimental data from various techniques is given. This program is characterized by the application of a universal response function, which allows many different physicochemical methods to be used to study equilibria without any modification of the program. It is also possible to refine additional parameters (electrode parameters, initial analytic concentration, etc). We have used the least-squares method with the weightings calculated according to the error propagation rule taking into account all independent variables. To minimize the function, singular Jacobian decomposition is applied. This allows control of its range and forms a set of parameters, determined from the experimental data.

引用

页码：2105 / 2112

页数：8

共 27 条

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