DIASTEREOSELECTIVE CLEAVAGE OF BETA-GLUCOSYLSULFOXIDES BY BETA-GLUCOSIDASE

被引：8

作者：

KARTHAUS, O ^{[1
]}

SHODA, S ^{[1
]}

KOBAYASHI, S ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC ENGN,DEPT MOLEC CHEM & ENGN,SENDAI,MIYAGI 980,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(00)86297-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Phenyl beta-D-glucopyranosyl sulfoxide and p-nitrophenyl beta-D-glucopyranosyl sulfoxide have been diastereoselectively cleaved by beta-glucosidases. Both distereomers can be selectively cleaved, depending on the origin of beta-glucosidase.

引用

页码：2213 / 2216

页数：4

共 9 条

[1] BETA-GLUCOSIDES OF AROMA COMPONENTS FROM PETALS OF ROSA SPECIES - ASSAY, OCCURRENCE, AND BIOSYNTHETIC IMPLICATIONS [J].

ACKERMANN, IE ;

BANTHORPE, DV ;

FORDHAM, WD ;

KINDER, JP ;

POOTS, I .

JOURNAL OF PLANT PHYSIOLOGY, 1989, 134 (05) :567-572

[2]

FLOWERS HM, 1979, ADV ENZYM, V48

[3]

HIROI K, 1989, TOHOKU YAKKA DAIGAKU, V36, P1

[4]

JONES JB, 1985, TETRAHEDRON REPORT, V203, P3351

[5]

KARTHAUS O, IN PRESS J CHEM S P1

[6]

KARTHAUS O, 1994, 67TH ANN M CHEM SOC, P866

[7] A ONE-STEP SYNTHESIS OF THE CICLAMYCIN TRISACCHARIDE [J].

RAGHAVAN, S ;

KAHNE, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (04) :1580-1581

[8] CELLULASE-CATALYZED, STEREOSELECTIVE SYNTHESIS OF OLIGOSACCHARIDES [J].

SHODA, S ;

OBATA, K ;

KARTHAUS, O ;

KOBAYASHI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) :1402-1404

[9]

White AR, 1982, CELLULOSE OTHER NATU

← 1 →