CLUSTER CHEMISTRY .76. A NEW C2 COMPLEX FROM REACTIONS OF RU5(MU-5-C2PPH2)(MU-PPH2)(CO)13 WITH PYRIDINE - X-RAY STRUCTURE OF RU5(MU-5-C2)(MU-PPH2)2(CO)11(PY)2

被引：16

作者：

ADAMS, CJ

BRUCE, MI

SKELTON, BW

WHITE, AH

机构：

[1] UNIV ADELAIDE,DEPT PHYS & INORGAN CHEM,JORDAN LABS,ADELAIDE,SA 5001,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 423卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0022-328X(92)83026-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between Ru5(mu-5-C2PPh2)(mu-PPh2)(CO)13 (1) and pyridine results in the formation of Ru5(mu-5-C2)(mu-PPh2)2(CO)11(py)2 (5) which has been fully characterised by an X-ray structure determination. The cluster core consists of an Ru4 butterfly metallated at a wingtip. A C2 ligand, formed by cleavage of the P-C(sp) bond in 1, is attached to all metal atoms, although one of the carbons has only a weak interaction with the hinge atoms. The overall C2Ru5 geometry is a distorted capped trigonal bipyramid, an Ru-C edge of which is bridged by the fifth Ru atom.

引用

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页码：97 / 104

页数：8

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