TEMPERATURE JUMP INDUCTION OF ISOMERIZATION DYNAMICS OF ALKALI-HALIDE CLUSTERS

被引：19

作者：

HEIDENREICH, A

SCHEK, I

SCHARF, D

JORTNER, J

机构：

[1] School of Chemistry, Tel-Aviv University, Tel-Aviv

来源：

ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS | 1991年 / 20卷 / 1-4期

关键词：

33.80; -; b; 35.20; i; 36.40. + d;

D O I：

10.1007/BF01543979

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The time resolved dynamics of diffusionless cube --> ring isomerization of the Na4Cl4 cluster was interrogated by constant energy molecular dynamics simulations, utilizing the first passage time method. The non-reactive isomerization induced by nonselective vibrational excitation is well accounted for in terms of the statistical RRK theory, opening avenues for experimental exploration of time-resolved cluster isomerization dynamics.

引用

页码：227 / 229

页数：3

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