SYNTHESIS AND REACTIVITY OF ALKYNYLOXY MOLYBDENUM CARBENE COMPLEXES - FORMATION OF CYCLOPROPYL SUBSTITUTED DIHYDROFURANS AND DIHYDROPYRANS

被引:16
作者
HARVEY, DF
BROWN, MF
机构
[1] Department of Chemistry, 0506 University of California, San Diego La Jolla
基金
美国国家卫生研究院;
关键词
D O I
10.1016/S0040-4039(00)92349-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Alkynyloxycarbene complexes of molybdenum have been found to readily cyclize to give cyclopropyldihydrofurans and cyclopropyldihydropyrans upon thermolysis in the presence of methyl acrylate.
引用
收藏
页码:5223 / 5226
页数:4
相关论文
共 17 条
[1]   SYNTHESIS OF SOME NOVEL TRIFLUOROMETHANESULFONATES AND THEIR REACTIONS WITH ALCOHOLS [J].
BEARD, CD ;
BAUM, K ;
GRAKAUSK.V .
JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (21) :3673-3677
[2]   SYNTHESIS OF A CHELATED TUNGSTEN CARBENE ALKENE COMPLEX AND ITS CONVERSION TO A CYCLOPROPANE [J].
CASEY, CP ;
VOLLENDORF, NW ;
HALLER, KJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (13) :3754-3764
[3]   INTRAMOLECULAR CYCLOPROPANATION AND OLEFIN METATHESIS REACTIONS OF (CO)5W=C(OCH2CH2CH=CHOCH3)C6H4-PARA-CH3 [J].
CASEY, CP ;
HORNUNG, NL ;
KOSAR, WP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) :4908-4916
[4]   GENERATION AND SPECTROSCOPIC OBSERVATION OF A TUNGSTEN CARBENE ALKENE INTERMEDIATE IN CYCLOPROPANE FORMATION [J].
CASEY, CP ;
SHUSTERMAN, AJ .
ORGANOMETALLICS, 1985, 4 (04) :736-744
[5]  
CASEY CP, 1973, SYNTH INORG METAL OR, V3, P249
[6]   REACTIONS OF [ACETOXY(2-FURYL)CARBENE]PENTACARBONYLCHROMIUM [J].
CONNOR, JA ;
JONES, EM .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (21) :3368-&
[7]   UBERGANGSMETALL-CARBEN-KOMPLEXE .2. PHENYLMETHOXYCARBEN- UND METHYLMETHOXYCARBEN-PENTACARBONYLCHROM -MOLYBDAN -WOLFRAM UND -CYCLOPENTADIENYL-DICARBONYL-MANGAN [J].
FISCHER, EO ;
MAASBOL, A .
CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (07) :2445-&
[8]  
HARVEY DF, 1990, TETRAHEDRON LETT, V31, P2529
[9]   MOLYBDENUM CARBENE COMPLEXES - TRAPPING OF INSITU GENERATED VINYLCARBENE COMPLEXES WITH ELECTRON-POOR OLEFINS [J].
HARVEY, DF ;
BROWN, MF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (21) :7806-7807
[10]  
HOYE TR, COMMUNICATION