GALLIUM DICHLORIDE-MEDIATED REDUCTIVE FRIEDEL-CRAFTS REACTION

被引：15

作者：

HASHIMOTO, Y ^{[1
]}

HIRATA, K ^{[1
]}

KIHARA, N ^{[1
]}

HASEGAWA, M ^{[1
]}

SAIGO, K ^{[1
]}

机构：

[1] UNIV TOKYO, FAC ENGN, DEPT SYNTHET CHEM, BUNKYO KU, TOKYO 113, JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(00)60971-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of gallium dichloride, carbonyl compounds reacted with anisole to give alkylated anisoles in good yields. It was suggested that the adducts were obtained by way of the reduction of the carbonyl compounds followed by the Friedel-Crafts reaction in a one-pot. This is the first organic synthetic method with gallium dichloride, low valent gallium.

引用

页码：6351 / 6354

页数：4

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