1-CYANO-3-(1H)-1,2-BENZIODOXOLS - STABLE CYANOIODINANES AND EFFICIENT REAGENTS FOR DIRECT N-ALKYL CYANATION OF N,N-DIALKYLARYLAMINES

被引：126

作者：

ZHDANKIN, VV

KUEHL, CJ

KRASUTSKY, AP

BOLZ, JT

MISMASH, B

WOODWARD, JK

SIMONSEN, AJ

机构：

[1] Chemistry Department, University of Minnesota-Duluth, Duluth

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 44期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(95)01720-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyanobenziodoxols 2 and 4 can be prepared from benziodoxols 1 or 3 and cyanotrimethylsilane in the form of stable, crystalline compounds. Cyanobenziodoxol 2 reacts with N,N-dimethylarylamines under mild conditions to afford N-(cyanomethyl)-N-methylarylamines 6 in excellent yields.

引用

收藏

页码：7975 / 7978

页数：4

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