INSERTION OF VINYLSILANE INTO THE RUTHENIUM-SILICON BOND - DIRECT EVIDENCE FOR THE NON-METALLACARBENE MECHANISM OF SILYLALKENE DISPROPORTIONATION

被引：80

作者：

MARCINIEC, B

PIETRASZUK, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950002003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible insertion of the vinylsilane molecule into the Ru-Si bond occurs in two different ways to give E-l,2-bis(silyl)ethene and 1,1-bis(silyl)ethene which, in combination with the previous experiments by Wakatsuki et al., provides-convincing evidence for a non-metallacarbene mechanism of silylalkene disproportionation.

引用

页码：2003 / 2004

页数：2

共 12 条

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