AQUEOUS HIGH-TEMPERATURE CHEMISTRY OF CARBOCYCLES AND HETEROCYCLES .5. MONOSUBSTITUTED BENZENES WITH A 2 CARBON-ATOM SIDE-CHAIN OXYGENATED AT THE BETA-POSITION

被引：17

作者：

KATRITZKY, AR ^{[1
]}

LUXEM, FJ ^{[1
]}

SISKIN, M ^{[1
]}

机构：

[1] EXXON RES & ENGN CO,CORP RES SCI LAB,ANNANDALE,NJ 08801

来源：

ENERGY & FUELS | 1990年 / 4卷 / 05期

关键词：

D O I：

10.1021/ef00023a019

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

2-Phenylethanol undergoes dehydration to styrene and to bis(2-phenylethyl) ether under both thermolysis and aquathermolysis conditions: small amounts of reduction and elimination of the side chain also occur. Phenylacetic acid is thermolyzed to form dibenzyl ketone and toluene, but the reaction is inhibited by water although a small amount of decarboxylation is observed in the presence of base. Phenylacetaldehyde is highly reactive and forms a wide variety of higher molecular weight products under both thermolysis and aquathermolysis conditions, mostly arising via aldol condensation reactions. © 1990, American Chemical Society. All rights reserved.

引用

页码：514 / 517

页数：4

共 14 条

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ENERGY & FUELS, 1990, 4 (05) :493-498

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