DETECTION AND CHEMICAL CHARACTERIZATION OF POLYCYCLIC AROMATIC HYDROCARBON AEROSOLS BY MEANS OF LASER-INDUCED FLUORESCENCE

被引:8
作者
NIESSNER, R
KRUPP, A
机构
[1] Institute of Hydrochemistry, Technical University of Munich, München, D-8000
关键词
D O I
10.1002/ppsc.19910080106
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Laser-induced and time-resolved aerosol fluorescence is introduced as an analytical technique for the qualitative and quantitative determination of surface-bound polycyclic aromatic hydrocarbons (PAHs). The analytical figures of merit are evaluated by studying the fluorescent properties (emission wavelengths and temporal behavior) of PAHs adsorbed on submicrometer NaCl particles. In addition to singly adsorbed PAHs on NaCl particles, a three-component PAH adsorbate system is characterized. Detection limits are in the range 5 ng/m3 (e.g. for anthanthrene).
引用
收藏
页码:23 / 28
页数:6
相关论文
共 15 条
[1]  
Grimmer G., Environmental Carcinogens: Polycyclic Aromatic Hydrocarbons, (1983)
[2]  
Pott F., Steinhoff D., Prüfung von PAH und PAH‐haltigen Emissionen und Immissionen im Subkutan‐Test, VDI‐Bericht, 358, pp. 317-322, (1980)
[3]  
Levsen K., The Analysis of Diesel Particulate, Fresenius Z. Anal. Chem., 331, pp. 467-478, (1988)
[4]  
Niessner R., The Chemical Response of the Photoelectric Aerosol Sensor (PAS) to Different Aerosol Systems, J. Aerosol Sci., 17, pp. 705-714, (1986)
[5]  
Niessner R., In‐Situ‐Photoemission an PAH‐beschichteten Aerosolen, Fresenius Z. Anal. Chem., 329, pp. 406-409, (1987)
[6]  
Niessner R., Walendzik G., The Photoelectric Aerosol Sensor as a Fast‐Responding and Sensitive Detection System for Cigarette Smoke Analysis, Fresenius Z. Anal. Chem., 333, pp. 129-133, (1989)
[7]  
Niessner R., Hemmerich B., Wilbring P., Aerosol Photoemission for Quantification of Polycyclic Aromatic Hydrocarbons in Simple Mixtures Adsorbed on Carbonaceous and Sodium Chloride Aerosols, Anal. Chem., 62, pp. 2071-2074, (1990)
[8]  
Niessner R., Robers W., Krupp A., Fiber Optical Sensor System Using a Tunable Laser for Detection of PAHs on Particles and in Water, SPIE, 1172, pp. 145-157, (1989)
[9]  
Allegrini I., Omenetto N., Laser‐Induced Fluorescence and Raman Scattering for Real Time Measurement of Suspended Particulate, Matter. Environ. Sci. Technol., 13, pp. 349-350, (1979)
[10]  
Jandris L., Force R., Determination of Polynuclear Aromatic Hydrocarbons in Vapor Phase by Laser‐Induced Molecular Fluorescence, Anal. Chim. Acta, 151, pp. 19-27, (1983)