NEW POLYAZA TRIS-FERROCENE AND TRIS-2,2'-BIPYRIDYL MACROBICYCLIC CRYPTAND MOLECULES - ISOLATION OF HOMO-POLYMETALLIC AND HETERO-POLYMETALLIC ZINC(II) AND COPPER(I) CRYPTATES CONTAINING EXTERNALLY COORDINATED RUTHENIUM(II) CATIONS

被引:48
作者
BEER, PD
KOCIAN, O
MORTIMER, RJ
SPENCER, P
机构
[1] UNIV BIRMINGHAM,DEPT CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND
[2] UNIV TECHNOL LOUGHBOROUGH,DEPT CHEM,LOUGHBOROUGH LE11 3YU,LEICS,ENGLAND
关键词
D O I
10.1039/c39920000602
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New multisite ligands containing either three peripherally linked ferrocene redox centres (L1,L3) or three externally orientated 2,2'-bipyridyl transition metal recognition sites (L2,L4) have been prepared and their homo- and hetero-polymetallic zinc(II) and copper(I) cryptates incorporating in the case of L2 and L4 externally coordinated ruthenium(II) cations have been isolated.
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页码:602 / 604
页数:3
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