NOVEL AMPHOTERIC 2,5-FUROQUINONOID-CONTAINING P-TERPHENOQUINONE ANALOGS GIVING BOTH A STABLE RADICAL-ANION AND A STABLE RADICAL-CATION

被引:7
作者
TAKAHASHI, K [1 ]
GUNJI, A [1 ]
AKIYAMA, K [1 ]
机构
[1] TOHOKU UNIV, INST CHEM REACT SCI, SENDAI, MIYAGI 980, JAPAN
关键词
D O I
10.1246/cl.1994.863
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel p-terphenoquinone analogues incorporating a central dihydrofurandiylidene skeleton have been synthesized. These quinones gave a stable radical cation and a stable radical anion on one-electron redox reactions showing an amphoteric property even though they db not contain any sulfur atom as an integral component. The radical cation and the radical anion of the tetra-t-butyl derivative have been characterized by EPR spectroscopy.
引用
收藏
页码:863 / 866
页数:4
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