HOMOGENEOUS CATALYSIS - USE OF CHIRAL TITANOCENE COMPLEXES FOR ASYMMETRIC CATALYTIC DIELS-ALDER REACTIONS

被引：35

作者：

ODENKIRK, W ^{[1
]}

BOSNICH, B ^{[1
]}

机构：

[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stable, chiral diaquo titanocene complex is an excellent catalyst for certain Diets-Alder reactions giving good enantioselectivity which indicates that catalysis occurs by metal rather than by proton activation of the dienophile.

引用

页码：1181 / 1182

页数：2