RELATIONSHIP BETWEEN ELECTRON-TRANSFER AND THE STRUCTURE OF A QUINONE-LINKED ZINC PORPHYRIN WITH A FLEXIBLE PEPTIDE SPACER

被引：13

作者：

HAYASHI, T

TAKIMURA, T

HITOMI, Y

OHARA, T

OGOSHI, H

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 05期

关键词：

D O I：

10.1039/c39950000545

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvent-dependent conformational change of the covalently linked porphyrin-peptide-quinone triad 1, as determined by H-1 NMR and electronic absorption spectra, obviously reflects an intramolecular electron transfer reaction from the zinc porphyrin to quinone in both polar and nonpolar solvents.

引用

收藏

页码：545 / 546

页数：2

相关论文

共 20 条

[1] MOLECULAR RECOGNITION .16. MOLECULAR RECOGNITION OF QUINONES - 2-POINT HYDROGEN-BONDING STRATEGY FOR THE CONSTRUCTION OF FACE-TO-FACE PORPHYRIN QUINONE ARCHITECTURES [J].

AOYAMA, Y ;

ASAKAWA, M ;

MATSUI, Y ;

OGOSHI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) :6233-6240

[2]

BALZANI V, 1991, SUPRAMOLECULAR PHOTO

[3] ELECTRON-TUNNELING IN A COFACIAL ZINC PORPHYRIN-QUINONE CAGE MOLECULE - NOVEL TEMPERATURE AND SOLVENT DEPENDENCE [J].

DELANEY, JK ;

MAUZERALL, DC ;

LINDSEY, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (03) :957-963

[4] QUINONE-CAPPED METALLOPORPHYRINS - SYNTHESIS AND COORDINATION CHEMISTRY [J].

GANESH, KN ;

SANDERS, JKM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (23) :1129-1131

[5] CHARGE SEPARATION IN CAROTENOPORPHYRIN - QUINONE TRIADS - SYNTHETIC, CONFORMATIONAL, AND FLUORESCENCE LIFETIME STUDIES [J].

GUST, D ;

MOORE, TA ;

LIDDELL, PA ;

NEMETH, GA ;

MAKINGS, LR ;

MOORE, AL ;

BARRETT, D ;

PESSIKI, PJ ;

BENSASSON, RV ;

ROUGEE, M ;

CHACHATY, C ;

DESCHRYVER, FC ;

VANDERAUWERAER, M ;

HOLZWARTH, AR ;

CONNOLLY, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) :846-856

[6] SPECIFIC MOLECULAR RECOGNITION VIA MULTIPOINT HYDROGEN-BONDING UBIQUINONE ANALOGS PORPHYRIN HAVING 4 CONVERGENT HYDROXYL-GROUPS PAIRING [J].

HAYASHI, T ;

MIYAHARA, T ;

HASHIZUME, N ;

OGOSHI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) :2049-2051

[7] INTERMOLECULAR INTERACTION BETWEEN MULTIFUNCTIONAL PORPHYRIN AND UBIQUINONE ANALOGS [J].

HAYASHI, T ;

MIYAHARA, T ;

AOYAMA, Y ;

KOBAYASHI, M ;

OGOSHI, H .

PURE AND APPLIED CHEMISTRY, 1994, 66 (04) :797-802

[8] PREPARATION AND BINDING-AFFINITY OF NEW PORPHYRIN HOST MOLECULE FOR UBIQUINONE ANALOGS [J].

HAYASHI, T ;

MIYAHARA, T ;

AOYAMA, Y ;

NONOGUCHI, M ;

OGOSHI, H .

CHEMISTRY LETTERS, 1994, (09) :1749-1752

[9] DYNAMIC MOLECULAR RECOGNITION IN A MULTIFUNCTIONAL PORPHYRIN AND A UBIQUINONE ANALOG [J].

HAYASHI, T ;

ASAI, T ;

HOKAZONO, H ;

OGOSHI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) :12210-12211

[10] DETECTION OF THE INVERTED REGION IN THE PHOTOINDUCED INTRAMOLECULAR ELECTRON-TRANSFER OF CAPPED PORPHYRINS [J].

IRVINE, MP ;

HARRISON, RJ ;

BEDDARD, GS ;

LEIGHTON, P ;

SANDERS, JKM .

CHEMICAL PHYSICS, 1986, 104 (02) :315-324