MODEL REACTIONS FOR BACTERIAL BIOLUMINESCENCE

被引：13

作者：

MCCAPRA, F ^{[1
]}

LEESON, P ^{[1
]}

机构：

[1] UNIV SUSSEX, SCH MOLEC SCI, BRIGHTON BN1 9QJ, SUSSEX, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1976年 / 24期

关键词：

D O I：

10.1039/c39760001037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acid-catalyzed addition of H2O2 to n-butyl vinyl ether gave a separable mixture of hydroperoxides, 3 of which undergo chemiluminescent reactions in acetonitrile with 1,3,10-trimethylisoalloxazinium perchlorate, [which is an alternative model for the intermediate in the bioluminescent oxidation of long-chain aldehyde to fatty acid by bacterial luciferase], in the presence of triethylamine. The flavin analog catalyzes the decomposition of the peroxides.

引用

页码：1037 / 1038

页数：2

共 19 条

[1]

[Anonymous], 1973, PROG ORG CHEM

[2] QUINOXALINE DERIVATIVES .3. CYCLISATION OF 3-4-DIHYDRO-3-OXOQUINOXALINE-2-CARBOXYUREIDES TO 1-2-3-4-TETRAHYDRO-3-OXOQUINOXALINE-2-SPIRO-5'-HYDANTOINS [J].

CLARKLEWIS, JW .

JOURNAL OF THE CHEMICAL SOCIETY, 1957, (JAN) :422-430

[3]

Cormier M J, 1973, Fortschr Chem Org Naturst, V30, P1

[4] POSTULATED MECHANISM FOR BIOLUMINESCENT OXIDATION OF REDUCED FLAVIN MONONUCLEOTIDE [J].

EBERHARD, A ;

HASTINGS, JW .

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1972, 47 (02) :348-&

[5]

Hamilton G. A., 1971, PROGRESS BIOORGANIC, V1, P83

[6] SPECTRAL PROPERTIES OF AN OXYGENATED LUCIFERASE FLAVIN INTERMEDIATE ISOLATED BY LOW-TEMPERATURE CHROMATOGRAPHY [J].

HASTINGS, JW ;

BALNY, C ;

LEPEUCH, C ;

DOUZOU, P .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1973, 70 (12) :3468-3472

[7]

HEMMERICH P, 1973, ANN NY ACAD SCI, V211, P13

[8]

HUNT BJ, 1967, CHEM IND-LONDON, P1868

[9] DIRECTION OF CLEAVAGE OF PRIMARY OZONIDES IN METHANOLIC OZONOLYSES OF STYRENE PROPENYLBENZENE AND 2-METHYLPROPENYLBENZENE [J].

KEAVENEY, WP ;

BERGER, MG ;

PAPPAS, JJ .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (05) :1537-&

[10] SIMPLE SYNTHESIS OF A 4A-HYDROPEROXY ADDUCT OF A 1,5-DIHYDROFLAVINE - PRELIMINARY STUDIES OF A MODEL FOR BACTERIAL LUCIFERASE [J].

KEMAL, C ;

BRUICE, TC .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1976, 73 (04) :995-999

← 1 2 →