LEWIS-BASE-DICTATED STRUCTURAL VARIATIONS IN SODIUM AMIDE CHEMISTRY - X-RAY CRYSTAL-STRUCTURES OF PHENYL(2-PYRIDYL)AMIDOSODIUM WITH HEXAMETHYLPHOSPHORIC TRIAMIDE (HMPA) AND WITH PENTAMETHYLDIETHYLENETRIAMINE (PMDETA)

被引：28

作者：

ANDREWS, PC

CLEGG, W

MULVEY, RE

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014401

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two crystalline adducts of sodium amide 1 and 2 adopt contrasting binuclear structures, as revealed by X-ray diffraction. Thus, the bidentate anions are linked to the Na+ ions in a terminal manner in 1 but in a bridging manner in 2. Each structure also displays unusual donor-acceptor coordinations, with HMPA bridging to Na+ in 1, while only two of the three available PMDETA nitrogen centers complex to Na+ in 2.

引用

页码：1440 / 1441

页数：2

共 11 条

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