ON STEROIDS .366. PREPARATION OF UNLABELED AND [H-3] LABELED EPITESTOSTERONE AND ITS METABOLITES

被引：10

作者：

KASAL, A ^{[1
]}

FUKSOVA, K ^{[1
]}

POUZAR, V ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI, INST NUCL BIOL & RADIOCHEM, CS-14220 PRAGUE 4, CZECHOSLOVAKIA

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1993年 / 58卷 / 03期

关键词：

D O I：

10.1135/cccc19930600

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cold as well as [H-3]-labelled substrates and metabolites IX - XI, XV, XVI, XX - XXII, XXIV, XXV and XXVIII were prepared by catalytic hydrogenation of epitestosterone (VIII) and LAMBDA1-dehydroepitestosterone (XIII). The key step in the preparation of compound XXVIII was reaction of 3beta-tosylates XXVI and XXX with potassium nitrite in dimethyl sulfoxide.

引用

页码：600 / 611

页数：12

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