ASYMMETRIC-SYNTHESIS OF ALPHA-AMINO BETA-HYDROXY PHOSPHONIC-ACIDS VIA BINAP-RUTHENIUM CATALYZED HYDROGENATION

被引：72

作者：

KITAMURA, M

TOKUNAGA, M

PHAM, T

LUBELL, WD

NOYORI, R

机构：

[1] NAGOYA UNIV, DEPT CHEM, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN

[2] UNIV MONTREAL, DEPT CHIM, MONTREAL, PQ H3C 3J7, CANADA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 32期

关键词：

D O I：

10.1016/0040-4039(95)01135-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

BINAP-Ru catalyzed hydrogenation of configurationally labile alpha-amido beta-keto phosphonic esters gives the (R,R)- or (S,S)-alpha-amido beta-hydroxy phosphonic esters in a highly enantio- and diastereoselective manner.

引用

页码：5769 / 5772

页数：4

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