LIPASE-CATALYZED ESTERIFICATION AT HIGH-PRESSURE

被引：20

作者：

KNEZ, Z

HABULIN, M

机构：

[1] Faculty of Technical Sciences, Dept. Chemical Engineering, University of Maribor, SLO-62000, Maribor

来源：

BIOCATALYSIS | 1994年 / 9卷 / 1-4期

关键词：

ESTERIFICATION; SUPERCRITICAL FLUIDS; LIPASE;

D O I：

10.3109/10242429408992113

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

From the comparation of esterification between oleic acid and oleyl alcohol, catalyzed by the Mucor miehei immobilized lipase in a batch stirred tank reactor, in a solvent free system and system where the solvent was supercritical carbon dioxide it is obvious that reaction rates are higher at supercritical conditions than in the solvent free system. To obtain the data on the solubility of substrates and product (oleyl oleate) in supercritical carbon dioxide, fluid phase equilibria measurements in the static equilibrium cell have been done. The results showed that the temperature change between 30-degrees-C and 50-degrees-C doesn't affect the solubility of the substances in SC CO2 very much, but with higher pressure (between 100 and 300 bar) the solubilities of oleic acid, oleyl alcohol and oleyl oleate slightly increase. From the data it is obvious that oleic acid and oleyl alcohol have better solubility in supercritical CO2 than oleyl oleate and therefore the separation of both substrates from oleyl oleate with supercritical CO2 is possible.

引用

页码：115 / 121

页数：7

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