SYNTHESIS AND COMPLEXATION TO RUTHENIUM(II) AND IRON(III) MESO-TETRAPHENYLPORPHYRINS OF 2 NEW FLUORINATED ALKYL ISOCYANIDES - 2-MONOFLUOROETHYL ISOCYANIDE AND 2,2,2-TRIFLUOROETHYL ISOCYANIDE

被引：27

作者：

GEZE, C ^{[1
]}

LEGRAND, N ^{[1
]}

BONDON, A ^{[1
]}

SIMONNEAUX, G ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM ORGANOMET & BIOL LAB,CNRS,UA 415,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

INORGANICA CHIMICA ACTA | 1992年 / 195卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)83852-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New 2-monofluoroethyl isocyanide and 2,2,2-trifluoroethyl isocyanide ligands have been complexed to TPPRu(II) and TPPFe(III)OSO2CF3 in order to provide information on the fluorine effect on alkyl isocyanide binding. The comparison of IR and NMR data indicates a great similarity between the bonding properties of the fluorinated isocyanide and alkyl isocyanide ligands.

引用

页码：73 / 76

页数：4

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