ANODIC-OXIDATION OF SULFIDE IONS IN MOLTEN LITHIUM-FLUORIDE

被引：10

作者：

LLOYD, CL

GILBERT, JB

机构：

[1] Applied Research Laboratory, The Pennsylvania State University, State College

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1994年 / 141卷 / 10期

关键词：

D O I：

10.1149/1.2059149

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Cyclic voltammetry experiments have been performed on lithium sulfide in a lithium fluoride electrolyte at 1161 K using a graphite working electrode and a platinum quasi-reference electrode. Two distinct oxidation mechanisms are observed for the sulfide ions. The first oxidation produces sulfur and at a higher potential a disulfide species is proposed to have formed. Both oxidations appear to be reversible and diffusion controlled.

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页码：2642 / 2644

页数：3

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