TRIMETHYL ESTER OF COENZYME PQQ IN REDOX REACTIONS WITH TRANSITION-METALS - AN EFFICIENT SYSTEM FOR THE PALLADIUM-CATALYZED RING-OPENING REACTION OF ALPHA, BETA-EPOXYSILANE

被引：21

作者：

HIRAO, T

MURAKAMI, T

OHNO, M

OHSHIRO, Y

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 02期

关键词：

D O I：

10.1246/cl.1991.299

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient catalytic system for the palladium(II)-induced regioselective ring-opening oxidation reaction of alpha,-beta-epoxysilane was achieved by use of trimethyl ester of coenzyme PQQ under molecular oxygen. The redox cycle of the ester was performed with two different oxidation states of vanadium compounds, VCl2 and VO(OEt)3.

引用

页码：299 / 302

页数：4

共 27 条

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