NUCLEOPHILIC-ATTACK AT THE MESO POSITION OF A URANYL SAPPHYRIN COMPLEX

被引:46
作者
BURRELL, AK [1 ]
CYR, MJ [1 ]
LYNCH, V [1 ]
SESSLER, JL [1 ]
机构
[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712
关键词
D O I
10.1039/c39910001710
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Contrary to previous reports sapphyrin does react with uranyl cation to give a stable complex, which is no longer aromatic, having undergone attack by methoxide to give a new neutral complex; the synthesis, characterisation and X-ray structure of the new compound are described.
引用
收藏
页码:1710 / 1713
页数:4
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